Chapter 22: Summary of Major Reaction Mechanisms
Recommended Article: 【Organic Chemistry】 Organic Chemistry Table of Contents
Difficulty Level ★: Sophomore college level → Able to solve problems by rote memorization
Difficulty Level ★★: Senior college level → Capable of making deductions after some trials and errors
Difficulty Level ★★★: Exam candidate level for professional exams → Frequently tested complex reactions
Difficulty Level ★★★★: Highly difficult exam questions → Rarely tested complex reactions
1. Acetoacetic ester synthesis (Difficulty Level: ★)
2. Acyloin condensation (Difficulty Level: ★★)
3. Aldol addition (Difficulty Level: ★★)
4. Aldol condensation (Difficulty Level: ★★)
5. Arbuzov reaction (Difficulty Level: ★)
6. Arndt-Eistert synthesis (Difficulty Level: ★★)
7. Aza-Cope rearrangement (Difficulty Level: ★)
8. azo coupling (Difficulty Level: ★)
9. Baeyer-Villiger oxidation (Difficulty Level: ★★★)
10. Baylis-Hillman reaction (Difficulty Level: ★★★★)
11. Beckmann rearrangement (Difficulty Level: ★★★)
12. benzilic acid rearrangement (Difficulty Level: ★★★★)
13. benzoin condensation (Difficulty Level: ★★★★)
14. Birch reduction (Difficulty Level: ★)
15. Bischler-Napieralski reaction (Difficulty Level: ★★★★)
16. boronic acid Mannich reaction (Difficulty Level: ★★★★)
17. brown hydroboration (Difficulty Level: ★★)
18. Cannizzaro reaction (Difficulty Level: ★★★)
19. Claisen condensation (Difficulty Level: ★★)
20. Claisen rearrangement (Difficulty Level: ★)
21. Claisen-Schmidt reaction (Difficulty Level: ★★)
22. Clemmensen reduction (Difficulty Level: ★)
23. Cope elimination (Difficulty Level: ★★★)
24. Cope rearrangement (Difficulty Level: ★)
25. Corey-Posner-Whitesides-House Reaction (Difficulty Level: ★)
26. Corey-Seebach reaction (Difficulty Level: ★)
27. Cumene process (Difficulty Level: ★★★)
28. Curtius rearrangement (Difficulty Level: ★★★)
29. Darzens condensation (Difficulty Level: ★★)
30. Dess-Martin oxidation (Difficulty Level: ★)
31. Diazotisation (Difficulty Level: ★)
32. Dieckmann condensation (Difficulty Level: ★★)
33. Diels-Alder reaction (Difficulty Level: ★)
34. 1,3-dipolar cycloaddition (Difficulty Level: ★)
35. Eschweiler-Clarke reaction (Difficulty Level: ★★★★)
36. Ester pyrolysis (Difficulty Level: ★)
37. Ethylene coordination condensation using Cp2ZrCl2 and MAO (Difficulty Level: ★★★★)
38. Favorskii rearrangement (Difficulty Level: ★★★)
39. Fischer esterification (Difficulty Level: ★)
40. Friedel-Crafts acylation (Difficulty Level: ★)
41. Friedel-Crafts alkylation (Difficulty Level: ★)
42. Fries rearrangement (Difficulty Level: ★★★)
43. Gabriel synthesis (Difficulty Level: ★★)
44. Gattermann-Koch reaction (Difficulty Level: ★)
45. Grob fragmentation (Difficulty Level: ★★)
46. Grubbs reaction (Olefin metathesis) (Difficulty Level: ★★)
47. Haloform reaction (Difficulty Level: ★★)
48. Heck reaction (Difficulty Level: ★)
49. Hell-Volhard-Zelinsky(HVZ) reaction (Difficulty Level: ★★★★)
50. Hofmann elimination (Difficulty Level: ★★★)
51. Horner-Wadsworth-Emmons reaction (Difficulty Level: ★★★★)
52. Hundsdiecker reaction (Difficulty Level: ★★★★)
53. Ireland-Claisen rearrangement (Difficulty Level: ★★★★)
54. Johnson-Claisen rearrangement (Difficulty Level: ★★★★)
55. Johnson-Corey-Chaykovsky reaction (Difficulty Level: ★★★)
56. Jones oxidation (Difficulty Level: ★)
57. Knoevenagel condensation (Difficulty Level: ★★)
58. Kochi reaction (Difficulty Level: ★★★★)
59. Kolbe nitrile synthesis (Difficulty Level: ★)
60. Kolbe-Schmitt reaction (Difficulty Level: ★)
61. Malonic ester synthesis (Difficulty Level: ★★)
62. Mannich reaction (Difficulty Level: ★★)
63. McMurry reaction (Difficulty Level: ★★★★)
64. Meerwein-Ponndorf-Verley reduction (Difficulty Level: ★★★★)
65. Michael addition (Difficulty Level: ★★)
66. Mukaiyama aldol reaction (Difficulty Level: ★★)
67. Negishi coupling (Difficulty Level: ★)
68. oxy-Cope rearrangement (Difficulty Level: ★)
69. oxymercuration-demercuration reaction (Difficulty Level: ★)
70. ozonolysis (Difficulty Level: ★)
71. para-Claisen rearrangement (Difficulty Level: ★★)
72. Payne epoxidation (Difficulty Level: ★★)
73. Perkin’s condensation (Difficulty Level: ★★★★)
74. Pictet-Spengler reaction (Difficulty Level: ★★★)
75. Pinacol coupling reaction (Difficulty Level: ★★)
76. Pinacol rearrangement (Difficulty Level: ★★)
77.Pomeranz-Fritsch reaction (Difficulty Level: ★★★)
78. Reductive amination reaction (Difficulty Level: ★★)
79. Reimer-Tiemann reaction (Difficulty Level: ★★)
80. Reformatsky reaction (Difficulty Level: ★★★)
81. Ring expansion reaction (Difficulty Level: ★)
82. Ring contraction reaction (Difficulty Level: ★)
83. Ring formation reaction (Difficulty Level: ★)
84. Ring opening reaction (Difficulty Level: ★)
85. Ritter reaction (Difficulty Level: ★★)
86. Robinson annulation (Difficulty Level: ★★)
87. Rosenmund reduction (Difficulty Level: ★)
88. Sandmeyer reaction (Difficulty Level: ★)
89. Schmidt reaction (Difficulty Level: ★★★★)
90. semi-pinacol rearrangement (Difficulty Level: ★★)
91. Shapiro reaction (Difficulty Level: ★★★★)
92. Simmons-Smith reaction (Difficulty Level: ★)
93. Stetter reaction (Difficulty Level: ★★)
94. Strecker synthesis (Difficulty Level: ★)
95. Stork-Enamine reaction (Difficulty Level: ★★★)
96. Suzuki coupling (Difficulty Level: ★)
97. Swern oxidation (Difficulty Level: ★)
98. Tiffeneau-Demjanov rearrangement (Difficulty Level: ★★★)
99. tautomerization (Difficulty Level: ★)
100. Wilkinson catalyst (Difficulty Level: ★★★★)
101. Wilsmeier reaction (Difficulty Level: ★★)
102. Williamson ether synthesis (Difficulty Level: ★)
103. Wittig reaction (Difficulty Level: ★)
104. Wolff-Kishner reduction (Difficulty Level: ★★★)
105. Wolff rearrangement (Difficulty Level: ★★★)
106. Wurtz reaction (Difficulty Level: ★★)
107. Wurtz-Fittig reaction (Difficulty Level: ★★)
Input: 2022.02.02 17:55